The Ace of Wands represents the beginning of action, the spark of an idea. Given the fiery nature of Wands, we should expect that enthusiasm, passion, optimism along with a strong desire to achieve goals will be the fuel that energizes the initiation of action. The Six of Pentacles determines what sort of beginning the Ace is referring to. The Six of Pentacles is the card of exchange, of sharing and interaction. It's also a card of harmony and balance, so it often appears after times of strife. The combination of the Ace of Wands and the Six of Pentacles foretells the beginning of interaction in a balanced and harmonious way.
Possible manifestations of the Ace of Wands and the Six of Pentacles
The elements of the cards are Fire (Ace of Wands) and Earth (Six of Pentacles). The blending of Fire and Earth results in a neutral combination, which could be either negative or positive. However, since the Ace of Wands and the Six of Pentacles are cards that promise progress and expansion, the general feel of this combination would be a positive one. The Fire of the Ace of Wands energizes the Earth of the Six of Pentacles, while the Earth offers a solid base, that can't be easily destroyed by Fire.